SYNTHESIS AND CHARACTERIZATION OF SULFUR DONOR LIGAND (XANTHATE) COMPLEXE WITH MANGANESE (ll), IRON (ll), COBALT (ll), NIKEL (ll), COPPER (ll), AND ZINC (ll) AND THIER ADDUCT WITH NITROGEN BASE LIGANDE

  • HEJA IBRAHIM ADEL Dept. of Chemistry, College of Science, University of Duhok, Kurdistan Region-Iraq
  • SAAD.E. AL-MUKHTAR Dept. of Chemistry, College of Science, University of Mosul-Iraq
Keywords: Xanthate complexes, Complexes of [Manganese (ll), Iron (ll), Cobalt (ll), Nickel (ll), Copper (ll) & Zinc (ll)], Four-coordinate, sex-coordinate complexes, characterizations DFT of four coordinates

Abstract

New complexes and adducts of xanthate of the general formula [M(cyclopentyl xant.)2] and [M(cyclopentyl xant.)2.nL] Where M= Mn(ΙΙ) Fe(ΙΙ), Co(ΙΙ), Ni(ΙΙ), Cu(ΙΙ) and Zn(ΙΙ), and (cyclopentyl xant.)2=[Cyclopentyl xanthate ligand], n=2 L= Pyridine, 3-acetyl pyridine & Quinoline  n=1, L= ethylenediamine, (1,10)-phenanthroline,  the prepared complexes has been evaluated based on their magnetic, electrical, and physical characteristics. And spectral methods 1H-NMR of (cyclopentyl xant.) ligand, Based on the effective magnetic moment and electronic spectra, the structures of the kind [M(cyclopentyl xant.)2] indicate a tetrahedral geometry whereas structures of the kind [M(cyclopentyl xant.)2.nL]  has an octahedral geometry. The density functional theory (DFT) calculations of ligands and their complexes were performed by the DFT/B3LYP/6-311++G(d,p) method to obtain the optimized molecular geometry, the highest occupied molecular orbital (HOMO), the lowest unoccupied molecular orbital (LUMO), and electronic properties , thermodynamic parameters are done for four coordinates

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References

T. C. V, “Synthesis of metal xanthates and their application as latent catalysts for curing of epoxy resin GRADUATE SCHOOL OF LIFE SCIENCE AND,” 2015.
S. Sharma, R. Sachar, G. D. Bajju, and V. Sharma, “Nickel(II) complexes of m-ethylphenylxanthate with nitrogen donors and their biological screening,” Indian J. Chem., vol. 59, no. November, pp. 1618–1626, 2020.
M. Rumyantsev, I. A. Korablev, and S. Rumyantsev, “The reaction of potassium xanthates with five-membered cyclic carbonates: Selectivity of the underlying cascade reactions and mechanistic insights,” RSC Adv., vol. 10, no. 60, pp. 36303–36316, 2020, doi: 10.1039/d0ra07428d.
S. Z. Zard, “The xanthate route to six-membered carbocycles,” J. Chem. Res., vol. 46, no. 2, 2022, doi: 10.1177/17475198221088194.
K. Yang, G. Wang, F. Liu, X. Wang, and X. Chen, “Removal of multiple heavy metal ions using a macromolecule chelating flocculant xanthated chitosan,” Water Sci. Technol., vol. 79, no. 12, pp. 2289–2297, 2019, doi: 10.2166/wst.2019.230.
E. Vakalopoulou et al., “Synthesis and characterization of zinc di(: O -2,2-dimethylpentan-3-yl dithiocarbonates) bearing pyridine or tetramethylethylenediamine coligands and investigation of their thermal conversion mechanisms towards nanocrystalline zinc sulfide,” Dalt. Trans., vol. 49, no. 41, pp. 14564–14575, 2020, doi: 10.1039/d0dt03065a.
M. C. Kunene, “ve rs ity e Life cycle assessment of the To w n ve rs ity e To w,” 2014.
A. O. Görgülü, H. Çelikkan, and M. Arslan, “The synthesis, characterization and electrochemical behavior of transition metal complexes containing nitrogen heterocyclic sulphur donor ligand,” Acta Chim. Slov., vol. 56, no. 2, pp. 334–339, 2009.
JOHN MICHEL MURPHY, “some complexe containg donoer sulphur atom,” pp. 9–25, 2019.
Anamika et al., “Highly efficient structurally characterised novel precatalysts: Di- and mononuclear heteroleptic Cu(i) dixanthate/xanthate-phosphine complexes for azide-alkyne cycloadditions,” New J. Chem., vol. 43, no. 23, pp. 8939–8949, 2019, doi: 10.1039/c9nj01551e.
M. Chowdhry, “Theoretical study on reactivity of different sulfide collectors and theirbinding affinity toward Cu(II), Zn(II) and Pb(II) ions.,” no. Ii, 2015.
R. Ganesan and B. Viswanathan, “Physicochemical and catalytic properties of copper ethylenediamine complex encapsulated in various zeolites,” J. Phys. Chem. B, vol. 108, no. 22, pp. 7102–7114, 2004, doi: 10.1021/jp037765o.
S. E. Al- Mukhtar, H. F. Al-Katib, and L. A. Al-Nuaimy, “Preparation and Characterization of some Transition Metal Complexes with Crotyl xanthate Ligand and their Adducts with Nitrogen Bases,” Rafidain J. Sci., vol. 26, no. 1, pp. 49–55, 2017, doi: 10.33899/rjs.2017.138961.
F. K. AL-Jarah and S. E. AL-Mukhtar, “Preparation and Characterization of some Transition Metal Complexes with OleylXanthate and 1,10- Phenanthrolin,” Rafidain J. Sci., vol. 28, no. 2, pp. 228–234, 2019, doi: 10.33899/rjs.2019.159987.
A. Al-Fahdawi and E. Alsalihi, “Synthesis and Characterization of Iron(II), Cobalt(II), Nickel(II), Copper(II), and Zinc(II) Complexes Using Diphenylmethyl Xanthate Ligand,” ARO-The Sci. J. Koya Univ., vol. 6, no. 1, pp. 33–37, 2018, doi: 10.14500/aro.10243.
H. A. Mohammed and S. E. Al- Mukhtar, “Synthesis and Characterization of Mn(II), Fe(II) and Co(II) Complexes with 4-Hydroxypiperidinedithiocarbamate and their Adducts with Neutral Bases,” Rafidain J. Sci., vol. 25, no. 1, pp. 53–61, 2014, doi: 10.33899/rjs.2014.86068.
I. A. Al-Qasser, S. E. Al-Mukhtar, and N. F. Hana, “Synthesis and Characterization of 2-Butoxyethylxanthate Complexes with Iron(II), Cobalt(II), Nickel(II), Copper(II) and Zinc(II) and their Adducts with Nitrogen Base Ligands,” Rafidain J. Sci., vol. 25, no. 3, pp. 57–64, 2014, doi: 10.33899/rjs.2014.88644.
M. L. Childers and R. P. Planalp, “I. Complexation of iron(II), cobalt(II), nickel(II) and copper(II) by hexadentate tripodal aminopyridyl chelators II. Binding preferences for zinc(II) relative to nickel(II) and copper(II) in novel tetradentate aminopyridyl chelators,” vol. 1443601, no. Ii, p. 154, 2007,
M. Ali Dahi and A. J. Jarad, “Synthesis, characterization and biological evaluation of thiazolyl azo ligand complexes with some metal ions,” J. Phys. Conf. Ser., vol. 1664, no. 1, 2020, doi: 10.1088/1742-6596/1664/1/012090.
S. E. Lehman, “Spectroscopic studies of silica nanoparticles : magnetic resonance and nanomaterial-biological interactions,” 2016.
S. E. Al-Mukhtar and M. Th. Aghwan, “Synthesis and Characterization of 3-Methoxypropyldithiocarbamate Complexes with Iron(II), Cobalt(II), Nickel(II), Copper(II) and Zinc(II) and Their Adducts with Nitrogen Base Ligands,” Rafidain J. Sci., vol. 24, no. 7, pp. 50–59, 2013, doi: 10.33899/rjs.2013.77816.
B. F. Abrahams, B. F. Hoskins, E. R. T. Tiekink, and G. Winter, “Investigation of a New Xanthate Ligand. The Crystal and Molecular Structures of Nickel and Cadmium (Methoxyethyl)xanthates,” Aust. J. Chem., vol. 41, no. 7, pp. 1117–1122, 1988, doi: 10.1071/CH9881117.
Z.I.Takai, “Synthesis and Crystal Structure of o-Methoxyethyldithiocarbonato Nickel(II)Complex involving Tetramethylethylenediamine,” Asian J. Chem., vol. 30, no. 18, pp. 2424–2430, 2018.
T. E. Properties, “The Electronic Properties and Stereochemistry of the Copper(ii) Ion. Part,” no. 1678, 1968.
B. Derivatives, K. Marciniec, and B. Ewa, “Spectroscopic Investigations , Computational Analysis and,” CRYSTAL, vol. 76, 2021.
A. M. Fahim, A. M. Farag, A. Mermer, H. Bayrak, and Y. Şirin, “Synthesis of novel β-lactams: Antioxidant activity, acetylcholinesterase inhibition and computational studies,” J. Mol. Struct., vol. 1233, 2021, doi: 10.1016/j.molstruc.2021.130092.
H. Lgaz et al., “Evaluating the corrosion inhibition properties of novel 1,2,3-triazolyl nucleosides and their synergistic effect with iodide ions against mild steel corrosion in HCl: A combined experimental and computational exploration,” J. Mol. Liq., vol. 338, 2021, doi: 10.1016/j.molliq.2021.116522
Published
2022-11-20
How to Cite
ADEL, H. I., & AL-MUKHTAR, S. (2022). SYNTHESIS AND CHARACTERIZATION OF SULFUR DONOR LIGAND (XANTHATE) COMPLEXE WITH MANGANESE (ll), IRON (ll), COBALT (ll), NIKEL (ll), COPPER (ll), AND ZINC (ll) AND THIER ADDUCT WITH NITROGEN BASE LIGANDE. Journal of Duhok University, 25(2), 244-260. https://doi.org/10.26682/sjuod.2022.25.2.23
Section
Pure and Engineering Sciences