PHOTOCATALYTIC DEGRADATION OF EOSIN Yellowish DYE IN AQUEOUS SOLUTION USING TITANIUM DIOXIDE AS CATALYST: IMPACT OF VARIOUS PARAMETERS AND KINETIC STUDY
Keywords:
Dyeing, Semiconductors, PH, Temperature, First order
Abstract
Eosin Yellow, a type of heterocyclic dye consisting of bromine atoms, finds its applications in various industries, such as dyeing, printing, leather industry, and fluorescent pigment production. This study investigated the process of photocatalytic degradation of eosin yellowish dye in water solutions using titanium dioxide as a catalyst, as well as its degradation in the absence of semiconductors. The effect of specific factors including initial concentration of eosin yellowish dye and photo catalyst (TiO2), pH levels, and temperature on this degradation process was also tested. The results showed that increasing the concentration of TiO2 improved the above dye degradation. Moreover, it is found that shifting the pH from acidic to alkaline conditions enhanced dye degradation. This study also determined the order of eosin yellowish dye using integral rate laws and established that the degradation of the dye follows a first-order reaction at 517 nm
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References
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Atkin's, P., and Julio, D. (2006). physical chemistry (4th ed.). Oxford: Oxford University Press.
Anirudhan, T., S., and Rejeena, S., R. (2015). Photocatalytic Degradation of Eosin Yellow Using Poly(pyrrole-co-aniline)-Coated TiO2/Nanocellulose Composite under Solar Light. Journal of Materials,1-11.
Bandara, J., and Ranasinghe, R. ASS. (2007). The effect of MgO coating on photocatalytic activity of SnO2 for the degradation of chlorophenol and textile colorants; the correlation between the photocatalytic activity and the negative shift of flatband potential of SnO2. Applied Catalysis A: General. 319, 58-63.
Daneshvar, N., Ashassi–SorKhahi., N., and Tizpar, A. (2003). Decolourization of Organge II by elecrocoagulation. Separation and Purification Technology. 31, 153–162.
Elaziouti, A., Laouedj, N., and Bekka, A. (2011). Effect of pH Solution on the Optical Properties of Cationic Dyes in Dye/ Maghnia Montmorillonite Suspensions. Journal of Chemical Engineering & Process Technology, 21-5.
Fabian, A., U., Patrick, O., A., and Victoria, A., I. (2022). Biosorption of an Anionic Dye, Eosin Yellow onto Pineapple Peels: Isotherm and Thermodynamic Study. International Annals of science, 4,14-19,
Gouvêa, C., A., Wypych, F., Moraes, S., G., Durán, N., Nagata, N., and Peralta-Zamora., P. (2000). Semiconductor-assisted photocatalytic degradation of reactive dyes in aqueous solution. Chemosphere, 40, 433-40.
Haydar, A., M., Shinwar, A., I., Reving, A., R., Abraheem, A., M., Sherwan, M., S., and Idrees, S., K. (2018). Photo-catalytic degradation of Toluidine Blue Dye in aqueous medium Under Fluorescent Light. International Conference on Advanced Science and Engineering (ICOASE), Kurdistan Region, Iraq.
Ihab, A., T., Ihsan, H., Dakhel, Z., Kubba, and Ahmed, H., A. (2018). Degradation High Concentration of Eosin Yellowish Dye in Heterogeneous Catalyst Solution. Journal of Global Pharma Technology, 10, 704-709.
Jayanthi, K., Umadevi, M., Sukumar, C., Dhanakumar, S., and Pattabhi, S. Decolorization of Eosin Yellow Dye from Aqueous Solution by Electrocoagulation Process, 3,1, 2349 – 5456.
Mohammed, M., M., and Shinwar, A., I. (2020). Degradation of Congo Red Dye using Homogeneous Photo Fenton Catalyst Coupled with Oxygen Kinetics and Statistical Analysis. Asian Journal of Applied Chemistry Research, 6, 1-9.
Parsa, B., Vahidian, R., Soleymani, R,, and Abbasi, M. (2011). Removal of Acid Brown 14 in aqueous media by electrocoagulation: Optimization parameters and minimizing of energy consumption. Desalination, 278, 295–302.
Raad, N., S., and Salah-Aldin, N. (2019). Photodegradation of 2, 4, 5, 6- tetrachloroisophthalonitrile (chlorothalonil) by visible and ultraviolet light in the presence of Zno and TiO2. Science Journal of University of Zakho, 7, 79-88.
Rabindranathan, S., Suja, D., and Yesodharan, S. (2003). Photocatalytic degradation of phosphamidon on semiconductor oxides, Journal of Hazard Materiasl, 102, 217-229.
Rauf, M., Meetani, A., and Hisaidee, S. (2011). An overview on the photocatalytic degradation of azo dyes in the presence of TiO2 doped with selective transition metals. Desalination, 276,13-27.
Salam, A., Mohamed, A., Aboamera, N., M., Osman, T., A., and Khattab, A. (2018). Photocatalytic degradation of organic dyes using composite nanofibers under UV irradiation. Applied Nanoscience, 8,155-161.
Samuel, O., O., William, W., A., Francis O., S., Kumar S., and Penny, P., G. (2018). Photodegradation of Eosin Yellow Dye in Water under Simulated Solar Light Irradiation Using La–Doped ZnO Nanostructure Decorated on Graphene Oxide as an Advanced Photocatalyst. chemistry select, 3, 4, 1180-1188
Seema, A., and Babulal, R. (2009). Fluorescence spectrometric study of eosin yellow dye–surfactant interactions. Arabian Journal of Chemistry, 2, 7–12.
Shinwar, A., I., Salah-Aldin, N., and Anees, A. (2015). Photodegradation of Trifluralin in Suspension Aqueous Solution of Acetonitrile/Water. Msc. thesis (zakho: university of zakho).
Shinwar, A., I., Lazgin, A., J., and Khalid, M., O. (2021). Fabrication Of Novel Metal-Free Phosphorous Doped Boron Nitride As UV. Active Photo-Catalyst. Iranian journal of catalysis. 11 (4): 405-416.
Shinwar, A., I., Lazgin, A. J., and Khalid, M., O. (2022). Silver-Loaded Carbon and Phosphorous Co-Doped Boron Nitride Quantum Dots (Ag@CP-BNQDs) for Efficient Organic Waste Removal: Theoretical and Experimental Investigations. ACS Omega. 7 (42): 37620-37628.
Shinwar, A., I., Lazgin, A., J. and Khalid M., O. (2023). Efficient photo-Fenton catalysis using magnetic iron nanoparticles decorated boron nitride quantum dots: theoretical and experimental investigations. RSC Adv. 13, 6779–6792.
Zaied, M., and Bellakhal, N. (2009). Electrocoagulation treatment of black liquor from paper industry. Journal of Hazards and Material, 163, 995–1000
Published
2023-09-20
How to Cite
SALIH, R. N., KHALO, A. A. H. I. S., & AHMED, H. A. (2023). PHOTOCATALYTIC DEGRADATION OF EOSIN Yellowish DYE IN AQUEOUS SOLUTION USING TITANIUM DIOXIDE AS CATALYST: IMPACT OF VARIOUS PARAMETERS AND KINETIC STUDY . Journal of Duhok University, 26(2), 24-35. https://doi.org/10.26682/sjuod.2023.26.2.3
Section
Pure and Engineering Sciences
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