APPLICATION OF POLLUTION INDICES FOR HEAVY METAL CONTAMINATION ASSESSMENT IN SURFACE WATER OF DUHOK DAM (KURDISTAN REGION, IRAQ)

  • HAJAR AMEEN AMEEN Dept. of Soil and Water Science, College of Agriculture, University of Duhok, Duhok, Kurdistan region – Iraq
  • OMAR A.O. REKANI Dept. of Soil and Water Science, College of Agriculture, University of Duhok, Duhok, Kurdistan region – Iraq
  • VAHIL I. H. BARWARI Dept. of Soil and Water Science, College of Agriculture, University of Duhok, Duhok, Kurdistan region – Iraq
Keywords: Water Sources, Water Pollution, Heavy Metals, Pollution Indices, Duhok Dam

Abstract

Continuous monitoring and assessment of water sources in term of heavy metal is crucial to grantee their suitability for any purposes including human consumption. Accordingly, this study was conducted to assess surface water pollution of Duhok Dam in Kurdistan region of Iraq, in term of metal pollution indices. Surface water samples were collected from 6 different sites around the dam during dry (July to October, 2018) and wet (December to April 2019) seasons, and analyzed for heavy metals concentration including Chromium (Cr), Manganese (Mn), Iron (Fe), Copper (Cu), Zinc (Zn), lead (Pb), and Cadmium (Cd) using Atomic Absorption Spectrophotometer. Then, heavy metal pollution index (HPI), degree of contamination (Cd) and heavy metal evaluation index (HEI) was calculated for assessing overall quality of the water with regard to the total content of heavy metals. Results of individual parameters showed that, except Cd, the concentration of heavy metals at all the studied sites were lower than prescribed limits according to Iraqi's (IQS:417, 2001) and WHO (2017) standards. However, the results was also showed that the concentrations of Cd in most of the studied sites were higher than the permissible limits (3μg/L) depending on the recommended standards, indicating that there is a leaching of this metal into the water dam. Based on metal pollution indices values, despite of the existence of higher value of HPI in one situation, water samples from all studied sites were below the critical values. Concerning the seasonal variation, the concentrations of heavy metals and metal indices values were fluctuated throughout the seasons and different sites. Depending on these results, it can be concluded that the dam water can be used as safe water for drinking. However, higher concentration of Cd in some water samples could have negatives impacts on human health in long-term usage. Therefore, it can be suggested that simple treatments such as  granular activated carbon filtration of the study water before use is advisable for granting safe water supply to the citizens of this area

Downloads

Download data is not yet available.

References

 Abdullah E.J., Quality assessment for Shatt Al-Arab River using heavy metal pollution index and metal index. Journal of Environment and Earth Science, 3(5) (2013),114-120.
 Al-Barzingy Y.O.M., Water quality assessment for Duhok reservoir. ZANCO Journal of Pure and Applied Sciences, 30(6) (2018) 66-71. DOI: https://doi.org/10.21271/ZJPAS.30.6.6
 APHA, Standard methods for the examination of water and waste water. American Public Health Association, Washington DC, (2005).
 Backman B., Bodiš D., Lahermo P., Rapant S. and Tarvainen T., Application of a groundwater contamination index in Finland and Slovakia. Environmental Geology, 36(1-2) (1998), 55-64. https://doi.org/10.1007/s002540050320
 Bhardwaj R., Gupta A. and Garg J.K., Evaluation of heavy metal contamination using environmetrics and indexing approach for River Yamuna, Delhi stretch, India. Water Science, 31(1) (2017), 52-66. https://doi.org/10.1016/j.wsj.2017.02.002
 Bora M. and Goswami D.C., Water quality assessment in terms of water quality index (WQI): case study of the Kolong River, Assam, India. Applied Water Science, 7(6) (2017), 3125-3135.
 Brown R.M. McClelland N.I. Deininger R.A. and Tozer R.G., A Water Quality Index- Do We Dare, (1970). https://doi.org/10.1007/s13201-016-0451-y
 Brraich O.S. and Jangu S., Evaluation of water quality pollution indices for heavy metal contamination monitoring in the water of Harike Wetland (Ramsar Site), India. International Journal of Scientific and Research Publications, 5(2) (2015), 1-6.
 Drinking-Water Standard, (IQS:417), Central Organization for Quality Control and Standardization, Council of Ministers, Republic of Iraq, (2001).
 Duman F., Sezen G. and Tug G.N., Seasonal changes of some heavy metal concentrations in Sapanca Lake water, Turkey. Uluslararası Doğa ve Mühendislik Bilimleri Dergisi, (3) (2007), 25-28.
 Edet A.E. and Offiong O.E., Evaluation of water quality pollution indices for heavy metal contamination monitoring. A study case from Akpabuyo-Odukpani area, Lower Cross River Basin (southeastern Nigeria). GeoJournal, 57(4) (2002), 295-304. DOI: https://doi.org/10.1023/B:GEJO.0000007250.92458.de
 Ewaid S.H., Water quality evaluation of Al-Gharraf river by two water quality indices. Applied Water Science, 7(7) (2017), 3759-3765.DOI: https://doi.org/10.1007/s13201-016-0523-z
 Gautam R.K., Sharma S.K., Mahiya S. and Chattopadhyaya M.C., Contamination of heavy metals in aquatic media: transport, toxicity and technologies for remediation. Heavy metals in water: Presence, removal and safety, (2014), 1-24.DOI:10.1039/9781782620174-00001
 Hawrami K. and Mezuri H., Assessing Risks to Human Health from Potentially Toxic Elements in Drinking Water of Duhok Province/Kurdistan Region of Iraq. Journal of Environment Pollution and Human Health, 2(2) (2014), 44-51.DOI:10.12691/jephh-2-2-2
 Herojeet R., Rishi M.S. and Kishore N., Integrated approach of heavy metal pollution indices and complexity quantification using chemometric models in the Sirsa Basin, Nalagarh valley, Himachal Pradesh, India. Chinese Journal of Geochemistry, 34(4) (2015), 620-633. https://doi.org/10.1007/s11631-015-0075-1
 IQS, (Iraqi drinking water standard:417), Central Organization for Quality Control and Standardization, Council of Ministers, Republic of Iraq, (2001).
 Issaka S. and Ashraf M.A., Impact of soil erosion and degradation on water quality: a review. Geology, Ecology, and Landscapes, 1(1) (2017), 1-11. https://doi.org/10.1080/24749508.2017.1301053
 Khatri N. and Tyagi S., Influences of natural and anthropogenic factors on surface and groundwater quality in rural and urban areas. Frontiers in Life Science, 8(1) (2015), 23-39. https://doi.org/10.1080/21553769.2014.933716
 Mohammed R., The impact of the man activity in duhok dam watershed on the future of Duhok Dam Lake North-Iraq. In 1st International Applied Geological Congress, Department of Geology, Islamic Azad University-Mashad Branch, Iran, (2010), 26-28).
 Mohan S.V., Nithila P. and Reddy S.J., Estimation of heavy metals in drinking water and development of heavy metal pollution index. Journal of Environmental Science & Health Part A, 31(2) (1996), 283-289. https://doi.org/10.1080/10934529609376357
 Mohhamed N.I. and Bamarni K.A., Water quality monitoring of Duhok Dam (Kurdistan Region of Iraq). ZANCO Journal of Pure and Applied Sciences, 31(1) (2019), 7-16. DOI:https://doi.org/10.21271/ZJPAS.31.1.2
 Ndeda L.A. and Manohar S., Determination of heavy metals in Nairobi dam water,(Kenya). IOSR Journal of Environmental Science, Toxicology and Food Technology, 8(5) (2014), 68-73. DOI:10.9790/2402-08546873
 Prasad B. and Bose J., Evaluation of the heavy metal pollution index for surface and spring water near a limestone mining area of the lower Himalayas. Environmental Geology, 41(1-2) (2001), 183-188. https://doi.org/10.1007/s002540100380
 Prasad B. and Kumari S., Heavy metal pollution index of ground water of an abandoned open cast mine filled of the water quality of River Adyar, India. Bulletin of Environmental Contamination and Toxicology, 82(2) (2008), 211-217. DOI:10.1007/s10230-008-0050-8
 Prasad B. and Mondal K.K., The impact of filling an abandoned open cast mine with fly ash on ground water quality: a case study. Mine Water and the Environment, 27(1) (2008), 40-45. https://doi.org/10.1007/s10230-007-0021-5
 Priti P. and Paul B., Assessment of Heavy Metal Pollution in Water Resources and their Impacts: A Review. Journal of Basic and Applied Engineering Research, 3(8) (2016), 671-675.
 Reza R. and Singh G., Heavy metal contamination and its indexing approach for river water. International Journal of Environmental Science & Technology, 7(4) (2010), 785-792. https://doi.org/10.1007/BF03326187
 Shekha Y.A., Ismael H.M. and Ahmed A.A., Bacteriological and mycological assessment for water quality of Duhok reservoir, Iraq. Jordan Journal of Biological Sciences, 147(916) (2013), 1-8.DOI:10.12816/0001630
 Shigut D.A., Liknew G., Irge D.D. and Ahmad T., Assessment of physico-chemical quality of borehole and spring water sources supplied to Robe Town, Oromia region, Ethiopia. Applied Water Science, 7(1) (2017), 155-164. https://doi.org/10.1007/s13201-016-0502-4
 Toma J.J., Limnological study of Dokan, Derbendikhan and Duhok lakes, Kurdistan region of Iraq. Open Journal of Ecology, 3(1) (2013), 23-29.DOI:10.4236/oje.2013.31003
 Uzairu A., Okunola O.J., Wakawa R.J. and Adewusi S.G., Bioavailability studies of metals in surface water of River Challawa, Nigeria. Journal of Applied Chemistry, 2014(2014), Article ID 648453, 9p. http://dx.doi.org/10.1155/2014/648453
 Yisa J., Jimoh T.O. and Oyibo O.M., Underground water assessment using water quality index. Leonardo Journal of Sciences, 21 (2012), 33-42.
 Zarazua G., Ávila-Pérez P., Tejeda S., Barcelo-Quintal I. and Martínez T., Analysis of total and dissolved heavy metals in surface water of a Mexican polluted river by total reflection X-ray fluorescence spectrometry. Spectrochimica Acta Part B: Atomic Spectroscopy, 61(10-11) (2006), 1180-1184. https://doi.org/10.1016/j.sab.2006.06.010
 Zvinowanda C.M., Okonkwo J.O., Shabalala P.N. and Agyei N.M., A novel adsorbent for heavy metal remediation in aqueous environments. International Journal of Environmental Science & Technology, 6(3) (2009), 425-434. https://doi.org/10.1007/BF03326081
Published
2019-08-01
How to Cite
AMEEN AMEEN, H., REKANI, O. A., & BARWARI, V. I. H. (2019). APPLICATION OF POLLUTION INDICES FOR HEAVY METAL CONTAMINATION ASSESSMENT IN SURFACE WATER OF DUHOK DAM (KURDISTAN REGION, IRAQ). Journal of Duhok University, 22(1), 252-264. https://doi.org/10.26682/avuod.2019.22.1.24
Section
Agriculture and Veterinary Science