ZINC ADSORPTION IN DIFFERENT CALCAREOUS SOILS
Keywords:
Zinc adsorption, temperature effect and forms of Zinc
Abstract
Zinc adsorption was studied for ten selective representative soils according the difference amount of
clay content, calcium carbonate and organic matter in Duhok governorate, Iraqi-Kurdistan region
included (Kanimasi-1&2, Batofa, Zakho, Assih, Semeel, Khanke, Faydi, Zawita and Bamarny locations).
Samples were air dried and sieved through a 2-mm sieve to study the physical and chemical
characteristics of the soils, forms of zinc and it’s adsorption. Results showed the soluble, DTPA
extractable zinc (available), CaCl2 extractable zinc (exchangeable) and total zinc ranged between (0.29 –
0.94), (0.88 – 1.64), (1.71 – 2.05), and (12.25 – 56.15) mg kg-1
respectively. Negative significant correlation
found between soluble zinc with pH, also negative significant correlation found between DTPA extractable
zinc with exchangeable potassium, bicarbonate and available phosphorus but positive significant
correlation found between CaCl2 extractable zinc with pH, total–Zn negatively affected with pH and
positively with HCO3 and sand. Results demonstrated that by increasing added zinc concentration to
studied soil zinc will be adsorbed zinc adsorbed greatly at temperature 25°C and 48°C. In general total
zinc adsorbed at 25C° in six concentrations was less than zinc adsorbed at 48C°. At temperatures 25°C
and 48°C the high total amount of zinc adsorbed found in the soil of Zawita and Zakho respectively, but
the lower total zinc adsorbed observed in soil of Batofa and Kani masi-2. The quantity of adsorption
affected positively by presence of clay, calcium carbonate, active calcium carbonate and cation exchange
capacity and negatively affected by the ion concentration of bicarbonate, calcium, potassium, organic
matter and sand content.
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References
Akay, A. and Doulati, B., 2012. The effect of soil
properties on Zn adsorption. Journal of
International Environmental Application and
Science, 7(1), p.151.
Allison, L.E., 1965. Total carbon. In: C.A. Black (ed.)
Method of soil analysis, part2. Agronomy Amer.
Soc. of Argon, adison, Wis.9, pp.1367-1389.
Alloway, B. J., 2008. Zinc in Soils and crop nutrition.
Second edition, published by IZA and IFA.
Brussels, Belgium and Paris, France.
Alloway, B.J. 2004. Zinc in soils and crop nutrition.
First edition. International Zinc association
(IZA). Brussels, Belgium.
Ashraf, M.S., Ranjha, A.M., Yaseen, M., Ahmad, N.
and Hannan, A., 2008. Zinc adsorption behavior
of different textured calcareous soils using
Freundlich and Langmuir models. Pak. J. Agri.
Sci, 45(1), pp.6-10.
Athokpam, H.S., Ralte, L., Chongtham, N., Singh,
N.B., Devi, K.N., Singh, N.G. and Sharma, P.T.,
2018. Status and Forms of Zinc in Acidic Soils
of Imphal West District, Manipur (India). Int. J.
Curr. Microbiol. App. Sci, 7(4), pp.2349-2358
Aydinalp, C. and Cresser, M., 2003. The Background
Levels of Heavy Metals in Vertisols Under
Mediterran Tupe of Climate in the Region of
Turkey. Journal of Central European Agriculture
, 4 (4), pp. 279-29.
Barwari, V.I.H., 2013. Soil Physic-Chemical
Properties as Influenced by Slope Position
Under Different Vegetation Covers In Duhok
Governorate (Doctoral dissertation, M. Sc.
Thesis Submitted to the Council of the Faculty
of Agriculture and Forestry, University of
Duhok).
Chahal, D. S., Sharma, B. D. and Singh, P. K., 2005.
Distribution of forms of zinc and their
association with soil properties and uptake in
different soil orders in semi-arid soils of Punjab,
India. Communications in Soil Science and Plant
Analysis.36; 2857-2874.
Chittamart, N., Inkam, J., Ketrot, D. and
Darunsontaya, T., 2016. Geochemical fractionation and adsorption characteristics of
zinc in Thai major calcareous
soils. Communications in soil science and plant
analysis, 47(20), pp.2348-2363.
Estefan, G., Sommer, R. and Ryan, J., 2013. Methods
of soil, plant, and water analysis. A manual for
the West Asia and North Africa region, pp.170-
176.
Gavlak, R., Horneck, D., Miller, R.O. and Kotuby-
Amacher, J., 2003. Soil, plant and water
reference methods for the western region. WCC-
103 Publication, Fort Collins.
Hararah, M.A., Al-Nasir, F., El-Hasan, T. and Ala’a,
H., 2012. Zinc adsorption–desorption isotherms:
possible effects on the calcareous vertisol soils
from Jordan. Environmental Earth
Sciences, 65(7), pp.2079-2085.
Hosseinpur, A.R. and Motaghian, H., 2015. Evaluating
of many chemical extractants for assessment of
Zn and Pb uptake by bean in polluted
soils. Journal of soil science and plant
nutrition, 15(1), pp.24-34.
Hussain, S., Maqsood, M.A. and Rahmatullah, M.,
2010. Increasing grain zinc and yield of wheat
for the developing world: A Review. Emirates
Journal of Food and Agriculture, pp.326-339.
Kandali, G.G., Barua, N.G., Basumatary, A. Medhi,
B.K. and Kurmi, K., 2016. Zinc fractions and
their availability in wetland rice in acidic soil of
Assam. Journal of the Indian Society of Soil
Science 64(1): 58-65.
Kiekens, L., 1980. Adsorptieverschijnselen van zware
metalen in gronden (Doctoral dissertation, Ghent
University).
Kitundu, K.M.B. and Mrema, J.P., 2006. The Status of
Zn, Cu, Mil, and Fe in the Soils and Tea Leaves
of Kibena Tea Estates, Njombe,
Tanzania. Tanzania Journal of Agricultural
Sciences, 7(1).
Kumar, Pramod, Ashok Kumar, Pardeep Kumar, B. P.
Dhayni, U. P. Shahi, Satendra Kumar2, Robin
Kumar3 and Ashish Dwivedi., 2016. Nutrients
Status of Cultivated Soils of Ganga Canal Area
of Meerut District of Uttar Pradesh. International
Journal of Bio-resource and Stress Management,
7(4) Special: 606 – 613.
Kumar, M. and Babel, A.L., 2011. Available
micronutrient status and their relationship with
soil properties of Jhunjhunu Tehsil, District
Jhunjhunu, Rajasthan, India. Journal of
Agricultural Science, 3(2), p.97.
Loeppert, R.H. and Suarez, D.L., 1996. Carbonate and
gypsum. Methods of Soil Analysis: Part 3
Chemical Methods, 5, pp.437-474.
Makoi, J.H.J.R., 2016. Status of Fe, Cu, Zn and Mn
and their relationship with some physical
chemical properties in the soils of Sonjo and
Lupiro alluvial/flood plains in Kilombero and
Ulanga Districts, Morogoro,
Tanzania. Academia Journal of
Biotechnology, 4(3), pp.76-84.
Malakouti, M.J., Keshavarz, P. and Karimian, N.,
2008. A comprehensive approach towards
identification of nutrients deficiencies and
optimal fertilization for sustainable
agriculture. Tarbiatmodares University press,
132p.
Marschner, H. (1995). Mineral nutrition of higher
plants. London: Academic Press.
Nordberg, G. F., Nordberg, M., Fowler, B. A., &
Friberg, L., 2011. Handbook on the Toxicology
of Metals. Burlington: Elsevier Science, P. 928.
Orabi, A.A., Mashadi, H., Abdallah, A. and Morsy, M.,
1981. Effect of zinc and phosphorus on the grain
yield of corn (Zea mays L.) grown on a
calcareous soil. Plant and Soil, 63(2), pp.291-
294.
Padidar, M., 2015. Effect of soil properties on kinetic
zinc release. Res. J. Fish. Hydrobiol, 1010,
pp.12-15.
Papadopoulos, P. and Rowell, D.L., 1989. The
reactions of copper and zinc with calcium
carbonate surfaces. Journal of Soil
Science, 40(1), pp.39-48.
Pilbeam, D.J. and Barker, A.V., 2007. Handbook of
plant nutrition (No. 631.81 H236h). Florida, US:
CRC Press.
Ramzan, S., Bhat, M.A., Kirmani, N.A. and Rasool,
R., 2014. Fractionation of zinc and their
association with soil properties in soils of
Kashmir Himalayas. Ind. J. Agric. Soil Sci, 2,
pp.132-142.
Rowell, D. L., (1996). Soil science. Methods and
application. Reading. University of United
Kingdom.
Ryan, J. G. E.G. and A. A. Rashid., 2001. Soil and
plant analysis Laboratory Manual. ICARDA,
Aleppo, Syria, and NARC, Islamabad, Pakistan.
(2nd Ed.), pp: 139-140.
Saffari M, Yasrebi J, Karimian N, Shan XQ (2009).
Evaluation of three sequential extraction
methods for fractionation of zinc in calcareous
and acidic soils. Research Biological Science, 4:
848-857.
Sampranpiboon, P., Charnkeitkong, P. and Feng, X.,
2014. Equilibrium isotherm models for
adsorption of zinc (II) ion from aqueous solution on pulp waste. WSEAS Transactions on
Environment and Development, 10, pp.35-47.
Saxena, M., Das, A. and Choudhury, S., 2017.
Chemical fractionation of zinc and its
relationship with important properties of rice
grown soils. IJCS, 5(4), pp.1205-1211.
Shamsham, S. and Nassra, R., 2015. Fractionation of
zinc and their association with soil properties in
soils of governorate homs. Environmental and
Earth of Journal, 7(2), pp.118-126.
Singh, V.I.N.A.Y. and Umashankar, S.R., 2018. Zinc
fractions in paddy soils and their relationship
with soil properties. Annals of Plant and Soil
Research, 20(2), pp.148-152.
Soltanpour, P.N. and Workman, S., 1979.
Modification of the NH4 HCO3-DTPA soil test
to omit carbon black. Communications in Soil
Science and Plant Analysis, 10(11), pp.1411-
1420.
Soltanpour, P.N., 1991. Determination of nutrient
availability and elemental toxicity by AB-DTPA
soil test and ICPS.In Advances in soil
science (pp. 165-190). Springer, New York, NY.
Summer, M.E. and Miller, W.P., 1996. Methods of
Soil Analysis, Part 3, Chemical Methods, SSSA
Book Series, vol. 5. Soil Sci. Soc. Am.,
Madison, WI.
Toth, S.J., Prince, A.L., Wallace, A. and Mikkelsen,
D.S., 1948. Rapid quantitative determination of
eight mineral elements in plant tissue by a
systematic procedure involving use of a flame
photometer. Soil Science, 66(6), pp.459-466.
Uygur, V. and Rimmer, D.L., 2000. Reactions of zinc
with iron‐oxide coated calcite surfaces at
alkaline H. European Journal of Soil
Science, 51(3), pp.511-516.
Verma, B.C., Swaminathan, K. and Sud, K.C., 1977.
An improved turbidimetric procedure for the
determination of sulphate in plants and
soils. Talanta, 24(1), pp.49-50.
Vitosh, M.L., Warncke, D.D. and Lucas, R.E., 1994.
Zinc determine of crop and soil. Michigan State
University Extension.
Vodyanitskii, Y. N., 2010. Zinc forms in soils (Review
of publications). Eurasian Soil Science, 43 (3),
pp.269-277.
properties on Zn adsorption. Journal of
International Environmental Application and
Science, 7(1), p.151.
Allison, L.E., 1965. Total carbon. In: C.A. Black (ed.)
Method of soil analysis, part2. Agronomy Amer.
Soc. of Argon, adison, Wis.9, pp.1367-1389.
Alloway, B. J., 2008. Zinc in Soils and crop nutrition.
Second edition, published by IZA and IFA.
Brussels, Belgium and Paris, France.
Alloway, B.J. 2004. Zinc in soils and crop nutrition.
First edition. International Zinc association
(IZA). Brussels, Belgium.
Ashraf, M.S., Ranjha, A.M., Yaseen, M., Ahmad, N.
and Hannan, A., 2008. Zinc adsorption behavior
of different textured calcareous soils using
Freundlich and Langmuir models. Pak. J. Agri.
Sci, 45(1), pp.6-10.
Athokpam, H.S., Ralte, L., Chongtham, N., Singh,
N.B., Devi, K.N., Singh, N.G. and Sharma, P.T.,
2018. Status and Forms of Zinc in Acidic Soils
of Imphal West District, Manipur (India). Int. J.
Curr. Microbiol. App. Sci, 7(4), pp.2349-2358
Aydinalp, C. and Cresser, M., 2003. The Background
Levels of Heavy Metals in Vertisols Under
Mediterran Tupe of Climate in the Region of
Turkey. Journal of Central European Agriculture
, 4 (4), pp. 279-29.
Barwari, V.I.H., 2013. Soil Physic-Chemical
Properties as Influenced by Slope Position
Under Different Vegetation Covers In Duhok
Governorate (Doctoral dissertation, M. Sc.
Thesis Submitted to the Council of the Faculty
of Agriculture and Forestry, University of
Duhok).
Chahal, D. S., Sharma, B. D. and Singh, P. K., 2005.
Distribution of forms of zinc and their
association with soil properties and uptake in
different soil orders in semi-arid soils of Punjab,
India. Communications in Soil Science and Plant
Analysis.36; 2857-2874.
Chittamart, N., Inkam, J., Ketrot, D. and
Darunsontaya, T., 2016. Geochemical fractionation and adsorption characteristics of
zinc in Thai major calcareous
soils. Communications in soil science and plant
analysis, 47(20), pp.2348-2363.
Estefan, G., Sommer, R. and Ryan, J., 2013. Methods
of soil, plant, and water analysis. A manual for
the West Asia and North Africa region, pp.170-
176.
Gavlak, R., Horneck, D., Miller, R.O. and Kotuby-
Amacher, J., 2003. Soil, plant and water
reference methods for the western region. WCC-
103 Publication, Fort Collins.
Hararah, M.A., Al-Nasir, F., El-Hasan, T. and Ala’a,
H., 2012. Zinc adsorption–desorption isotherms:
possible effects on the calcareous vertisol soils
from Jordan. Environmental Earth
Sciences, 65(7), pp.2079-2085.
Hosseinpur, A.R. and Motaghian, H., 2015. Evaluating
of many chemical extractants for assessment of
Zn and Pb uptake by bean in polluted
soils. Journal of soil science and plant
nutrition, 15(1), pp.24-34.
Hussain, S., Maqsood, M.A. and Rahmatullah, M.,
2010. Increasing grain zinc and yield of wheat
for the developing world: A Review. Emirates
Journal of Food and Agriculture, pp.326-339.
Kandali, G.G., Barua, N.G., Basumatary, A. Medhi,
B.K. and Kurmi, K., 2016. Zinc fractions and
their availability in wetland rice in acidic soil of
Assam. Journal of the Indian Society of Soil
Science 64(1): 58-65.
Kiekens, L., 1980. Adsorptieverschijnselen van zware
metalen in gronden (Doctoral dissertation, Ghent
University).
Kitundu, K.M.B. and Mrema, J.P., 2006. The Status of
Zn, Cu, Mil, and Fe in the Soils and Tea Leaves
of Kibena Tea Estates, Njombe,
Tanzania. Tanzania Journal of Agricultural
Sciences, 7(1).
Kumar, Pramod, Ashok Kumar, Pardeep Kumar, B. P.
Dhayni, U. P. Shahi, Satendra Kumar2, Robin
Kumar3 and Ashish Dwivedi., 2016. Nutrients
Status of Cultivated Soils of Ganga Canal Area
of Meerut District of Uttar Pradesh. International
Journal of Bio-resource and Stress Management,
7(4) Special: 606 – 613.
Kumar, M. and Babel, A.L., 2011. Available
micronutrient status and their relationship with
soil properties of Jhunjhunu Tehsil, District
Jhunjhunu, Rajasthan, India. Journal of
Agricultural Science, 3(2), p.97.
Loeppert, R.H. and Suarez, D.L., 1996. Carbonate and
gypsum. Methods of Soil Analysis: Part 3
Chemical Methods, 5, pp.437-474.
Makoi, J.H.J.R., 2016. Status of Fe, Cu, Zn and Mn
and their relationship with some physical
chemical properties in the soils of Sonjo and
Lupiro alluvial/flood plains in Kilombero and
Ulanga Districts, Morogoro,
Tanzania. Academia Journal of
Biotechnology, 4(3), pp.76-84.
Malakouti, M.J., Keshavarz, P. and Karimian, N.,
2008. A comprehensive approach towards
identification of nutrients deficiencies and
optimal fertilization for sustainable
agriculture. Tarbiatmodares University press,
132p.
Marschner, H. (1995). Mineral nutrition of higher
plants. London: Academic Press.
Nordberg, G. F., Nordberg, M., Fowler, B. A., &
Friberg, L., 2011. Handbook on the Toxicology
of Metals. Burlington: Elsevier Science, P. 928.
Orabi, A.A., Mashadi, H., Abdallah, A. and Morsy, M.,
1981. Effect of zinc and phosphorus on the grain
yield of corn (Zea mays L.) grown on a
calcareous soil. Plant and Soil, 63(2), pp.291-
294.
Padidar, M., 2015. Effect of soil properties on kinetic
zinc release. Res. J. Fish. Hydrobiol, 1010,
pp.12-15.
Papadopoulos, P. and Rowell, D.L., 1989. The
reactions of copper and zinc with calcium
carbonate surfaces. Journal of Soil
Science, 40(1), pp.39-48.
Pilbeam, D.J. and Barker, A.V., 2007. Handbook of
plant nutrition (No. 631.81 H236h). Florida, US:
CRC Press.
Ramzan, S., Bhat, M.A., Kirmani, N.A. and Rasool,
R., 2014. Fractionation of zinc and their
association with soil properties in soils of
Kashmir Himalayas. Ind. J. Agric. Soil Sci, 2,
pp.132-142.
Rowell, D. L., (1996). Soil science. Methods and
application. Reading. University of United
Kingdom.
Ryan, J. G. E.G. and A. A. Rashid., 2001. Soil and
plant analysis Laboratory Manual. ICARDA,
Aleppo, Syria, and NARC, Islamabad, Pakistan.
(2nd Ed.), pp: 139-140.
Saffari M, Yasrebi J, Karimian N, Shan XQ (2009).
Evaluation of three sequential extraction
methods for fractionation of zinc in calcareous
and acidic soils. Research Biological Science, 4:
848-857.
Sampranpiboon, P., Charnkeitkong, P. and Feng, X.,
2014. Equilibrium isotherm models for
adsorption of zinc (II) ion from aqueous solution on pulp waste. WSEAS Transactions on
Environment and Development, 10, pp.35-47.
Saxena, M., Das, A. and Choudhury, S., 2017.
Chemical fractionation of zinc and its
relationship with important properties of rice
grown soils. IJCS, 5(4), pp.1205-1211.
Shamsham, S. and Nassra, R., 2015. Fractionation of
zinc and their association with soil properties in
soils of governorate homs. Environmental and
Earth of Journal, 7(2), pp.118-126.
Singh, V.I.N.A.Y. and Umashankar, S.R., 2018. Zinc
fractions in paddy soils and their relationship
with soil properties. Annals of Plant and Soil
Research, 20(2), pp.148-152.
Soltanpour, P.N. and Workman, S., 1979.
Modification of the NH4 HCO3-DTPA soil test
to omit carbon black. Communications in Soil
Science and Plant Analysis, 10(11), pp.1411-
1420.
Soltanpour, P.N., 1991. Determination of nutrient
availability and elemental toxicity by AB-DTPA
soil test and ICPS.In Advances in soil
science (pp. 165-190). Springer, New York, NY.
Summer, M.E. and Miller, W.P., 1996. Methods of
Soil Analysis, Part 3, Chemical Methods, SSSA
Book Series, vol. 5. Soil Sci. Soc. Am.,
Madison, WI.
Toth, S.J., Prince, A.L., Wallace, A. and Mikkelsen,
D.S., 1948. Rapid quantitative determination of
eight mineral elements in plant tissue by a
systematic procedure involving use of a flame
photometer. Soil Science, 66(6), pp.459-466.
Uygur, V. and Rimmer, D.L., 2000. Reactions of zinc
with iron‐oxide coated calcite surfaces at
alkaline H. European Journal of Soil
Science, 51(3), pp.511-516.
Verma, B.C., Swaminathan, K. and Sud, K.C., 1977.
An improved turbidimetric procedure for the
determination of sulphate in plants and
soils. Talanta, 24(1), pp.49-50.
Vitosh, M.L., Warncke, D.D. and Lucas, R.E., 1994.
Zinc determine of crop and soil. Michigan State
University Extension.
Vodyanitskii, Y. N., 2010. Zinc forms in soils (Review
of publications). Eurasian Soil Science, 43 (3),
pp.269-277.
Published
2020-12-15
How to Cite
RAMADHAN, P. I., & MEHMEDANY, L. A. M. (2020). ZINC ADSORPTION IN DIFFERENT CALCAREOUS SOILS. Journal of Duhok University, 23(2), 118-130. https://doi.org/10.26682/ajuod.2020.23.2.15
Section
Agriculture and Veterinary Science
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